Phd Position

vor 1 Tag


Munich, Deutschland Technische Universität München Vollzeit

**The group for Functional Nanomaterials at the Technical University of Munich investigates chemical and structural dynamics of functional surfaces such as small oxide-supported metal clusters with state-of-the-art micros-copy and spectroscopy surface science techniques. We offer a stimulating research environment in a multidisciplinary laboratory in one of the highest-ranked universities in Europe. This advertised PhD position is funded within our ERC project on cluster catalysts under ambient conditions.**

Oxide-supported clusters ( 100 atoms) exhibit attractive properties for industrial catalysis which can change even with the addition of a single atom. In this PhD project, size-selected metal clusters on reducible and non-reducible oxide supports will be compared regarding their stability, reactivity and structure. Specifically, we will use near ambient pressure X-ray photoelectron spectroscopy (NAP-XPS) to probe changes in the oxidation state of the clusters, monitor whether they become encapsulated (as for larger nanoparticles), investigate the influence of cluster charge state on reactivity, and study the stability window with regards to sinter resistance in different gas environments.
- and gas composition-dependent NAP-XPS experiments and in-depth data analysis at synchrotrons around the world (e.g. Berkeley, Lund, Trieste). To this purpose, you will prepare single crystal (e.g. TiO2(110)) or thin film (e.g. Al2O3) supports, generate size-selected metal clusters using a cluster source and characterize these systems under ambient conditions. Later, you will also participate in writing new beamtime proposals that reflect the progress of your thesis project. You will also be involved in the installation and operation of a new lab-based NAP-XPS at TUM. In addition, you will have the opportunity to learn about scanning tunneling microscopy to obtain complementary information about structural changes of clusters.

Required qualifications

**Offer**:
Application

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